Material Description
To
effectively protect reinforcing steel against corrosion, a coating
must provide a continuous film that will: resist penetration by salt
ions; resist the action of osmosis, adhere to and expand/contract
with the steel substrate; resist breakdown from weathering and
exposure; and be flexible and durable enough for handling.
Fusion-bonded epoxy coating satisfies all of these requirements. It
is a thermoset material, meaning that once it is cured, the coating
will not tend to soften with higher temperatures. It achieves its
beneficial properties as a result of a heat catalyzed chemical
reaction. Epoxy coating starts out as a dry powder. The powder is
produced by combining organic epoxy resins with appropriate curing
agents, fillers, pigments flow control agents. When heated, the
powder melts and its constituents react to form complex cross-linked
polymers.
Epoxy coatings are environmentally friendly materials. Unlike many
paints, the fusion-bonded epoxy coatings used for steel
reinforcement do not contain appreciable solvents or other
environmentally hazardous substances. Systems used to apply the
coating are very efficient, resulting in little material loss to the
atmosphere and little waste disposal.
Manufacturing Process
The
process of applying fusion-bonded epoxy coating to steel
reinforcement involves four major steps: surface preparation,
heating, powder application and curing. In most North American epoxy-coating
plants, bars are first coated in straight lengths and then
fabricated (i.e., cut to length and bent to shape). A few facilities
have the capabilities to coat reinforcing steel (both bars and
welded wire fabric) after it has been fabricated.
Surface Preparation
Proper surface preparation assures that maximum adhesion will
develop at the interface between the steel and the coating.
Reinforcing steel is blast-cleaned to a near white metal finish
using abrasive grit. This cleans the steel of contaminants, mill
scale and rust. It also roughens the surface in order to give it a
textured, anchor profile (i.e., the microscopic peaks and valleys on
the steel surface). The surface roughness "keys" the coating to the
steel and provides mechanical anchorage. Texturing the surface also
facilitates adhesion by increasing the exposed surface area of the
steel and by providing more opportunity for the coating to
chemically bond.
Chemical pre-treatments have been used to supplement blast cleaning.
Heating
After blast-cleaning, the bars are heated to approximately 450
degrees F. Using electrical induction heaters.
Fusion Bonding
The
heated bars are then passed through a powder spray booth where dry
epoxy powder is emitted from a number of spray nozzles. As the
powder leaves the spray nozzle, an electrical charge is imparted to
the particles. These electrically charged particles are attracted to
the grounded steel surface providing an even coverage of the coating.
When the dry powder hits the hot steel, it melts and flows into the
anchor profile and conforms to the ribs and deformations of the bar.
The heat also initiates a chemical reaction that causes powder
molecules to form the complex cross-linked polymers that give the
epoxy coating its beneficial properties.
Curing
Following powder application, the coating is allowed to cure for a
short period (approximately 30 seconds) during which it hardens. To
facilitate handling, the curing period is often followed by an air
or water quench that quickly reduces the bar temperature.
How Epoxy Coating Protects
Fusion-bonded epoxy coating principally protects against corrosion
by serving as a barrier that isolates the steel from the oxygen,
moisture, and chloride ions that are needed to cause corrosion.
Epoxy coating also has a high electrical resistance, which blocks
the flow of electrons that make up the electrochemical process of
corrosion. In addition to serving as a circuit breaker, the coating
protects in way that is less obvious: coating reduces the size and
number of potential cathode sites, which will limit the rate of any
corrosion reaction that could occur. In order for macrocell
corrosion to take place, a large area of steel surface is needed to
serve as the cathode where oxygen reduction can occur. |